BAUXITE

Bauxite is not a mineral. It is a rock formed from a laterite soil that has been severely leached of silica and other soluble materials in a wet tropical or subtropical climate. It is the primary ore of aluminum. Almost all of the aluminum that has ever been produced has been extracted from bauxite. 

Detailed description

Bauxite does not have a specific composition. It is a mixture of hydrous aluminum oxides, aluminum hydroxides, clay minerals and insoluble materials such as quartz, hematite, magnetite, siderite and goethite. The aluminum minerals in bauxite can include: gibbsite Al(OH)₃, boehmite AlO(OH), and, diaspore, AlO(OH). 

Physical Properties of Bauxite

 

Bauxite is typically a soft (H:1-3), white to gray to reddish brown material with a pisolitic structure, earthy luster and a low specific gravity (SG: 2.0-2.5). These properties are useful for identifying bauxite; however, they have nothing to do with bauxite's value or usefulness. This is because bauxite is almost always processed into another material with physical properties that are distinctly different from bauxite. 

Physical Properties of Bauxite
Chemical Classification
Color	white, gray, sometimes stained yellow, orange red, pink, brown or yellow by iron or included iron minerals
Streak	usually white but iron stain can discolor
Luster	dull, earthy
Diaphaneity	opaque
Cleavage	none
Mohs Hardness	1 to 3
Specific Gravity	2 to 2.5
Diagnostic Properties	often exhibits pisolitic structure, color
Chemical Composition	variable but always rich in aluminum oxides and aluminum hydroxides
Crystal System	n/a
Uses	primary ore of aluminum, also used as an abrasive

Bauxite Used for Aluminum Production

 

Bauxite is the principal ore of aluminum. The first step in producing aluminum is to crush the bauxite and purify it using the Bayer Process. In the Bayer Process the bauxite is washed in a hot solution of sodium hydroxide which leaches aluminum from the bauxite. The aluminum is precipitated out of solution in the form of aluminum hydroxide, Al(OH)₃. The aluminum hydroxide is then calcined to form alumina, Al₂O₃. 

Aluminum is smelted from the alumina using the Hall-Heroult Process. In the Hall-Heroult Process the alumina is dissolved in a molten bath of cryolite (Na₃AlF₆). Molten aluminum is removed from the solution by electrolysis. This process uses an enormous amount of electricity. Aluminum is usually produced where electricity costs are very low. 

Use of Bauxite as an Abrasive

 

Calcined alumina is a synthetic corundum, which is a very hard material (9 on the Mohs Hardness Scale). Calcined alumina is crushed, separated by size and used as an abrasive. Aluminum oxide sandpaper, polishing powders and polishing suspensions are made from calcined alumina. 

Sintered bauxite is often used as an sand-blasting abrasive. It is produced by crushing bauxite to a powder and then fusing it into spherical beads at very high temperature. These beads are very hard and very durable. The beads are then sorted by size for use in different types of sandblasting equipment and for different sandblasting applications. Their round shape reduces wear on the delivery equipment. 

Use of Bauxite as a Proppant

 

Sintered bauxite is also used as an oil field proppant. In drilling for oil and natural gas the reservoir rock is often fractured by pumping fluids into the well under very high pressures. The pressure builds up to very high levels that cause the reservoir rock to fracture. When fracturing occurs water and suspended particles, known as "proppants" rush into the fractures and push them open. When the pumps are turned off the fractures close trapping the proppant particles in the reservoir. If an adequate number of crush-resistant particles remain in the reservoir the fractures will be "propped" open allowing for a flow of oil or natural gas out of the rocks and into the well. This process is known as hydraulic fracturing. 

Powdered bauxite can be fused into tiny beads at very high temperatures. These beads have a very high crush resistance and that makes them suitable as a proppant. They can be produced in almost any size and in a range of specific gravity. The specific gravity of the beads and their size can be matched to the viscosity of the hydraulic fracturing fluid and to the size of fractures that are expected to develop in the rock. Manufactured proppants provide a wide selection of grain size and specific gravity compared to a natural proppant known as frac sand. 

Substitutes for Bauxite

 

World bauxite resources are adequate for decades of production at current rates. Other materials could be used instead of bauxite for alumina production. Clay minerals, alunite, anorthosite, power plant ash and oil shale could be used to produce alumina but at higher costs, using different processes. Silicon carbide could be used in place of bauxite-based abrasives. Synthetic mullite could be used in place of bauxite-based refractories. 

Price

$1.7/kg

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